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KMID : 1024519990080020211
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Journal of the Environmental Sciences
1999 Volume.8 No. 2 p.211 ~ p.219
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Studies on the Adsorption Modeling of Cationic Heavy Metals(Pb, Cd) by the Surface Complexation Model
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Park Sang-Won
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Abstract
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Surface complexation models(SCMs) have been performed to predict metal ion adsorption behavior onto the mineral surface. Application of SCMs, however, requires a self-consistent approach to determine model parameter values. In this paper, in order to determine the metal ion adsorption parameters for the triple layer model(TLM) version of the SCM, we used the zeta potential data for Zeolite and Kaolinite, and the metal ion adsorption data for Pb(II) and Cd(II). Fitting parameters determined for the modeling were as follows ; total site concentration, site density, specific surface area, surface acidity constants, etc. Zeta potential as a new approach other than the acidic-alkalimetric titration method was adopted for simulation of adsorption phenomena. Some fitting parameters were determined by the trial and error method. Modeling approach was successful in quantitatively simulating adsorption behavior under various geochemical conditions.
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KEYWORD
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surface complexation models, TLM, adsorption modeling, zeta potential
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